Protected Silver Mirrors

08 Jul.,2024

 

Protected Silver Mirrors

The specifications to the right are measured data for Thorlabs' protected silver mirrors with a -P01 coating. Damage threshold specifications are constant for this coating type, regardless of the size or shape of the mirror.

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Laser Induced Damage Threshold Tutorial

The following is a general overview of how laser induced damage thresholds are measured and how the values may be utilized in determining the appropriateness of an optic for a given application. When choosing optics, it is important to understand the Laser Induced Damage Threshold (LIDT) of the optics being used. The LIDT for an optic greatly depends on the type of laser you are using. Continuous wave (CW) lasers typically cause damage from thermal effects (absorption either in the coating or in the substrate). Pulsed lasers, on the other hand, often strip electrons from the lattice structure of an optic before causing thermal damage. Note that the guideline presented here assumes room temperature operation and optics in new condition (i.e., within scratch-dig spec, surface free of contamination, etc.). Because dust or other particles on the surface of an optic can cause damage at lower thresholds, we recommend keeping surfaces clean and free of debris. For more information on cleaning optics, please see our Optics Cleaning tutorial.

Testing Method

Thorlabs' LIDT testing is done in compliance with ISO/DIS  and ISO specifications.

First, a low-power/energy beam is directed to the optic under test. The optic is exposed in 10 locations to this laser beam for 30 seconds (CW) or for a number of pulses (pulse repetition frequency specified). After exposure, the optic is examined by a microscope (~100X magnification) for any visible damage. The number of locations that are damaged at a particular power/energy level is recorded. Next, the power/energy is either increased or decreased and the optic is exposed at 10 new locations. This process is repeated until damage is observed. The damage threshold is then assigned to be the highest power/energy that the optic can withstand without causing damage. A histogram such as that below represents the testing of one BB1-E02 mirror.


The photograph above is a protected aluminum-coated mirror after LIDT testing. In this particular test, it handled 0.43 J/cm2 ( nm, 10 ns pulse, 10 Hz, Ø1.000 mm) before damage.

The photograph above is a protected aluminum-coated mirror after LIDT testing. In this particular test, it handled 0.43 J/cm( nm, 10 ns pulse, 10 Hz, Ø1.000 mm) before damage.

Example Test Data Fluence # of Tested Locations Locations with Damage Locations Without Damage 1.50 J/cm2 10 0 10 1.75 J/cm2 10 0 10 2.00 J/cm2 10 0 10 2.25 J/cm2 10 1 9 3.00 J/cm2 10 1 9 5.00 J/cm2 10 9 1

According to the test, the damage threshold of the mirror was 2.00 J/cm2 (532 nm, 10 ns pulse, 10 Hz, Ø0.803 mm). Please keep in mind that these tests are performed on clean optics, as dirt and contamination can significantly lower the damage threshold of a component. While the test results are only representative of one coating run, Thorlabs specifies damage threshold values that account for coating variances.

Continuous Wave and Long-Pulse Lasers

When an optic is damaged by a continuous wave (CW) laser, it is usually due to the melting of the surface as a result of absorbing the laser's energy or damage to the optical coating (antireflection) [1]. Pulsed lasers with pulse lengths longer than 1 µs can be treated as CW lasers for LIDT discussions.

When pulse lengths are between 1 ns and 1 µs, laser-induced damage can occur either because of absorption or a dielectric breakdown (therefore, a user must check both CW and pulsed LIDT). Absorption is either due to an intrinsic property of the optic or due to surface irregularities; thus LIDT values are only valid for optics meeting or exceeding the surface quality specifications given by a manufacturer. While many optics can handle high power CW lasers, cemented (e.g., achromatic doublets) or highly absorptive (e.g., ND filters) optics tend to have lower CW damage thresholds. These lower thresholds are due to absorption or scattering in the cement or metal coating.

Pulsed lasers with high pulse repetition frequencies (PRF) may behave similarly to CW beams. Unfortunately, this is highly dependent on factors such as absorption and thermal diffusivity, so there is no reliable method for determining when a high PRF laser will damage an optic due to thermal effects. For beams with a high PRF both the average and peak powers must be compared to the equivalent CW power. Additionally, for highly transparent materials, there is little to no drop in the LIDT with increasing PRF.

In order to use the specified CW damage threshold of an optic, it is necessary to know the following:

  1. Wavelength of your laser
  2. Beam diameter of your beam (1/e2)
  3. Approximate intensity profile of your beam (e.g., Gaussian)
  4. Linear power density of your beam (total power divided by 1/e2 beam diameter)

Thorlabs expresses LIDT for CW lasers as a linear power density measured in W/cm. In this regime, the LIDT given as a linear power density can be applied to any beam diameter; one does not need to compute an adjusted LIDT to adjust for changes in spot size, as demonstrated by the graph to the right. Average linear power density can be calculated using the equation below. 

The calculation above assumes a uniform beam intensity profile. You must now consider hotspots in the beam or other non-uniform intensity profiles and roughly calculate a maximum power density. For reference, a Gaussian beam typically has a maximum power density that is twice that of the uniform beam (see lower right).

Now compare the maximum power density to that which is specified as the LIDT for the optic. If the optic was tested at a wavelength other than your operating wavelength, the damage threshold must be scaled appropriately. A good rule of thumb is that the damage threshold has a linear relationship with wavelength such that as you move to shorter wavelengths, the damage threshold decreases (i.e., a LIDT of 10 W/cm at nm scales to 5 W/cm at 655 nm):

While this rule of thumb provides a general trend, it is not a quantitative analysis of LIDT vs wavelength. In CW applications, for instance, damage scales more strongly with absorption in the coating and substrate, which does not necessarily scale well with wavelength. While the above procedure provides a good rule of thumb for LIDT values, please contact Tech Support if your wavelength is different from the specified LIDT wavelength. If your power density is less than the adjusted LIDT of the optic, then the optic should work for your application. 

Please note that we have a buffer built in between the specified damage thresholds online and the tests which we have done, which accommodates variation between batches. Upon request, we can provide individual test information and a testing certificate. The damage analysis will be carried out on a similar optic (customer's optic will not be damaged). Testing may result in additional costs or lead times. Contact Tech Support for more information.

Pulsed Lasers

As previously stated, pulsed lasers typically induce a different type of damage to the optic than CW lasers. Pulsed lasers often do not heat the optic enough to damage it; instead, pulsed lasers produce strong electric fields capable of inducing dielectric breakdown in the material. Unfortunately, it can be very difficult to compare the LIDT specification of an optic to your laser. There are multiple regimes in which a pulsed laser can damage an optic and this is based on the laser's pulse length. The highlighted columns in the table below outline the relevant pulse lengths for our specified LIDT values.

Pulses shorter than 10-9 s cannot be compared to our specified LIDT values with much reliability. In this ultra-short-pulse regime various mechanics, such as multiphoton-avalanche ionization, take over as the predominate damage mechanism [2]. In contrast, pulses between 10-7 s and 10-4 s may cause damage to an optic either because of dielectric breakdown or thermal effects. This means that both CW and pulsed damage thresholds must be compared to the laser beam to determine whether the optic is suitable for your application.

Pulse Duration t < 10-9 s 10-9 < t < 10-7 s 10-7 < t < 10-4 s t > 10-4 s Damage Mechanism Avalanche Ionization Dielectric Breakdown Dielectric Breakdown or Thermal Thermal Relevant Damage Specification No Comparison (See Above) Pulsed Pulsed and CW CW

When comparing an LIDT specified for a pulsed laser to your laser, it is essential to know the following:

  1. Wavelength of your laser
  2. Energy density of your beam (total energy divided by 1/e2 area)
  3. Pulse length of your laser
  4. Pulse repetition frequency (prf) of your laser
  5. Beam diameter of your laser (1/e2 )
  6. Approximate intensity profile of your beam (e.g., Gaussian)

The energy density of your beam should be calculated in terms of J/cm2. The graph to the right shows why expressing the LIDT as an energy density provides the best metric for short pulse sources. In this regime, the LIDT given as an energy density can be applied to any beam diameter; one does not need to compute an adjusted LIDT to adjust for changes in spot size. This calculation assumes a uniform beam intensity profile. You must now adjust this energy density to account for hotspots or other nonuniform intensity profiles and roughly calculate a maximum energy density. For reference a Gaussian beam typically has a maximum energy density that is twice that of the 1/e2 beam.

Now compare the maximum energy density to that which is specified as the LIDT for the optic. If the optic was tested at a wavelength other than your operating wavelength, the damage threshold must be scaled appropriately [3]. A good rule of thumb is that the damage threshold has an inverse square root relationship with wavelength such that as you move to shorter wavelengths, the damage threshold decreases (i.e., a LIDT of 1 J/cm2 at nm scales to 0.7 J/cm2 at 532 nm):

You now have a wavelength-adjusted energy density, which you will use in the following step.

Beam diameter is also important to know when comparing damage thresholds. While the LIDT, when expressed in units of J/cm², scales independently of spot size; large beam sizes are more likely to illuminate a larger number of defects which can lead to greater variances in the LIDT [4]. For data presented here, a <1 mm beam size was used to measure the LIDT. For beams sizes greater than 5 mm, the LIDT (J/cm2) will not scale independently of beam diameter due to the larger size beam exposing more defects.

The pulse length must now be compensated for. The longer the pulse duration, the more energy the optic can handle. For pulse widths between 1 - 100 ns, an approximation is as follows:

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Use this formula to calculate the Adjusted LIDT for an optic based on your pulse length. If your maximum energy density is less than this adjusted LIDT maximum energy density, then the optic should be suitable for your application. Keep in mind that this calculation is only used for pulses between 10-9 s and 10-7 s. For pulses between 10-7 s and 10-4 s, the CW LIDT must also be checked before deeming the optic appropriate for your application.

Please note that we have a buffer built in between the specified damage thresholds online and the tests which we have done, which accommodates variation between batches. Upon request, we can provide individual test information and a testing certificate. Contact Tech Support for more information.

[1] R. M. Wood, Optics and Laser Tech. 29, 517 ().
[2] Roger M. Wood, Laser-Induced Damage of Optical Materials (Institute of Physics Publishing, Philadelphia, PA, ).
[3] C. W. Carr et al., Phys. Rev. Lett. 91, ().
[4] N. Bloembergen, Appl. Opt. 12, 661 ().

First Surface Mirrors

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Common types of metal-coated mirrors, e.g. silver mirrors as are widely used in households, have their reflecting metal coating on the back side of a glass substrate (typically with an additional protection layer behind). In contrast to that approach, a first surface mirror, also called front surface mirror, has the reflecting coating on the front surface. That leads to various advantages over the first explained second surface mirrors, which are explained in the following section.

Figure 1:

Comparison of second surface and first surface mirrors. In the former case, the incident light travels through the transparent mirror substrate, and a secondary reflection from the front surface can occur.

Ordinary dielectric mirrors can in principle also be considered as first surface mirrors, but the term is usually applied only to a metal-coated mirrors. These can be made with different types of substrates &#; not only with glass, but e.g. also with metallic substrates, e.g. with rectangular or circular front surfaces, and with flat or curved surfaces.

Consequences of Front Reflection

For a first surface mirror, the reflected light does not need to propagate through the mirror substrate. That has the following consequences for its performance, when comparing with a second surface mirror:

  • The mirror substrate cannot reduce the reflectivity by absorption in certain wavelength regions. Therefore, front surface mirrors are preferable in situations where area wide low-loss reflection bands (e.g. in the infrared) are required.
  • Wavefront distortions due to optical inhomogeneities of the substrate cannot occur. The substrate only needs to be sufficiently flat.
  • For non-normal incidence of light, one avoids the transverse beam offset due to propagation in the glass substrate. In addition, in imaging applications one does not obtain ghost images due to the additional (weaker) front surface reflection of a second surface mirror.
  • For normal incidence, strong chromatic dispersion based on interference of contributions from front and back surface reflections is avoided. (For details of such effects, see the article on Gires&#;Tournois interferometers.)

For many applications in optics, the mentioned advantages are vital; some examples:

  • Laser mirrors (e.g. for CO2 lasers) generally need to be first surface mirrors.
  • Imaging applications generally need them for avoiding ghost images.
  • Broadband mirrors for spectroscopy are also usually made as front surface mirrors.

Therefore, first surface mirrors are quite common in professional optics. However, compared with back surface mirrors, they have the important disadvantage of being substantially more sensitive. The front surface may be touched, and a metal coating on the front surface is substantially more sensitive than a bare glass surface. For example, fingerprints can easily cause oxidation of the metal, and it may not be possible to clean such mirrors while retaining the full optical quality. Also, moisture or aggressive gases may cause oxidation of the mirror coating.

Protected and Enhanced Mirrors

In order to mitigate the sensitivity problem, and partly also for further improving the reflectivity, first surface mirrors are often made as protected or enhanced mirrors. This means that the metal layer is covered with a thin layer or multiple layers of a dielectric material such as amorphous SiO2 (silica) or Si3N4 (silicon nitride), which protects the coating particularly against oxidation (tarnish) and to a lower extent against scratches.

Strictly speaking, the main reflection will no longer occur at the front surface, when there is a dielectric coating on the metal layer. That coating, however, is very thin, and therefore often not considered as providing an additional surface.

For enhancing the reflectivity, one often uses multilayer dielectric coatings; this leads to enhanced metal coatings e.g. for enhanced silver mirrors. One effectively combines the large reflection bandwidth of a metallic mirror with the higher reflectivity and damage threshold of a dielectric mirror. In some cases, the coating is also optimized concerning chromatic dispersion &#; mostly for use in ultrafast lasers.

A potential disadvantage of additional coatings arises from their deviating thermal expansion coefficients. This can cause problems particularly when mirrors need to be operated in wide temperature regions. That is the case for optical telescopes, for example.

Examples

Here are some examples of protected and enhanced metal-coated mirrors:

  • Protected aluminum mirrors are relatively cheap mirrors for the visible and near-IR spectral region. They have a protective coating, e.g. made of silicon monoxide, but not particularly enhanced optical properties.
  • There are UV-enhanced aluminum mirrors with particularly high reflectivity for ultraviolet light down to &approx;250 nm. The enhancement of reflectivity, achieved with a dielectric multilayer coating, is typically obtained in a wide spectral range, i.e., also in the visible region. Besides the optical properties, the durability is also enhanced.
  • Similarly, IR-enhanced gold mirrors are available, which have a high reflectivity in the near or even mid infrared, e.g. up to 20 μm.
  • Ultrafast-enhanced silver mirrors have a very high reflectivity and low chromatic dispersion over the whole wavelength band of titanium&#;sapphire lasers (750&#; nm). The coating also protects against the tarnishing of the silver, but it is still better to keep such mirrors in a dry environment.

It is also possible to apply laser line coatings, which can enhance the reflectivity at one or more specific laser lines.

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